劉賓元

劉賓元

劉賓元,男,河北工業大學高分子化學與物理專業教授。

基本信息

教育情況] b]

1992.09-1994.07泰安師範專科學校化學系
1994.09-1996.07學士曲阜師範大學化學系
1996.09-1998.10 碩士 中科院長春應化所 無機化學專業
1998.10-2001.12 博士 中科院長春應化所 高分子化學與物理專業

工作經歷

2009.3- 中科院長春套用化學研究所 高級訪問學者
2008.12- 河北工業大高分子科學與工程系 教授
2006.7-2007.07 韓國釜山國立大學高分子科學與工程系 訪問學者
2003.03-2008.12 河北工業大高分子科學與工程系 副教授
2002.02-2003.03 韓國漢城國立大學分子科學與工程系 博士後
2001.12-2003.03 中科院長春套用化學研究所 助理研究員

教學科研工作

承擔本科生“高分子材料基礎”、“高分子材料發展動向”、“高分子化學與物理實驗”、“高分子化學實驗”和“專業外語”等課程教學工作;為研究生講授“可控合成”, “高分子現代分析技術”(學位課),“高分子化學”(學位課)等課程教學工作。目前主持教育部科學技術研究重點項目、河北省科學技術研究與發展計畫、天津市自然科學基金項目、河北省自然科學基金項目、中國石油天然氣股份有限公司科學創新研究與技術開發項目各1項;主持完成國家自然科學基金、教育部留學人員科研基金項目各1項,作為第一主研人參與完成國家自然科學基金1項。在J Polym Chem Part A、Polym Degrad Stab、React Function Polym、J Appl Poly Sci、Macromol Res等期刊發表研究論文30餘篇,SCI收錄21篇,SCI引證30餘次;會議論文數十篇;授權國家發明專利2項(第1發明人)。

承擔的科研項目

1. 天津市自然科學基金“醯亞胺基聚降冰片烯低介電常數材料的製備及性能的研究”(08JCYBJC02500)(2008-2010,負責人)
2. 河北省自然科學基金“功能降冰片烯加成類聚合物的合成與性能研究”(B2008000009)(2008-2010, 負責人)
3. 河北省科技支撐計畫, “聚丁烯-1製備專用Ziegler-Natta催化劑的開發”(09215110D)(2009-2011,負責人)
4. 中國石油天然氣股份有限公司科學研究與技術開發項目“可調控PE分子量分布的改性鈦-鎂催化劑研究”(2009-2010,負責人)
5. 教育部留學人員科研基金“表面原子轉移自由基聚合製備具有核殼結構的納米複合材料的研究”(2005, 負責人)
6. 國家自然科學基金“不含氟的低介電常數納米孔聚降冰片烯的合成及性能研究”(50403013)(2005-2007,負責人)
7. 清華大學核能與新能源技術研究院 “超微顆粒的穩定化及在有機-無機複合材料中的套用研究”(2004-2005,負責人)
8. 清華大學核能與新能源技術研究院 “氧化鋯納米複合材料的研究”(2005-2006,負責人)
9. 中國石油天然氣股份有限公司科學創新研究與技術開發項目“聚丁烯-1樹脂合成技術開發” (2008D5006-05-02)(2009-2010,第2)
10. 國家自然科學基金“單一主催化劑多米諾催化乙烯共聚合成LLDPE研究”(50573018)(2006-2008,第2)
11. 河北省科學技術研究與發展計畫“稀土/橋聯聚倍半矽氧烷的超分子構築和發光性能”(08965110D) (2008-2010, 第2)
12. 中國石油天然氣股份有限公司科學研究與技術開發項目“透明易加工LLDPE聚合中試研究” (2007-2008)
13. 教育部科學技術研究重點項目“LTL型沸石單層薄膜的定向構築及其套用”(2008-2010,第3)

研究成果專利

1. 劉賓元, 田春英, 張莉 用於二氧化碳與環氧化合物共聚的催化劑及其製備方法,專利公開號:CN 1715307A(授權,ZL2005 1 0013808.4)
2. 劉賓元, 張莉 一種N-取代醯亞胺的製備方法 專利公開號CN1724518A (授權,ZL2005 1 0014591.9)
3. 劉賓元, 閆衛東, 章文軍, 王亞琴, 曲佳燕, 張莉 合成降冰片烯與馬來酸酐共聚物的方法,專利公開號 CN101045775 專利申請號200710057296.0
4. 劉賓元, 閆衛東, 李楊, 王曉亞, 曲佳燕, 張莉 含脂環基的聚N-取代降冰片烯醯亞胺及其製備方法,專利申請號CN: 200710057398.2 專利公開號:CN 101050254A
5. 劉賓元,劉寶興,曲佳燕,張旭,楊敏 一種聚醚醚酮類聚合物及其製備方法,專利申請號200910068352.X
6. 劉賓元,趙鑫,高延浩,張莉,曲佳燕,楊敏 用於二氧化碳與環氧化合物共聚的催化劑及其製備方法和套用,專利申請號200910068351.5
7. 閆衛東,楊 敏, 劉盤閣, 劉賓元,張 旭,胡文艷,郝小宇,沈曉莉 用於製備支化聚乙烯的多米諾催化體系及其套用方法,專利公開號CN101220107 (專利申請號200710058763.1)
8. 閆衛東,楊 敏,劉賓元,郝小宇,劉盤閣,溫麗芳,程 曼 以乙烯為唯一單體製備支化聚乙烯的茂金屬多米諾催化體系及其套用,專利公開號CN101392036 (專利申請號200810152817.5)
9. 閆衛東,張寧寧,任合剛,張國虹,劉賓元,楊 敏,張 旭 用於合成線形低密度聚乙烯的鈦/釩雙金屬催化劑及其製備方法和套用,專利公開號CN101220107(專利申請號200810052253.8)

代表論文

1. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang "Copolymerization of Carbon Dioxide and Propylene Oxide with Ln(CCl3COO)3-Based catalyst: the Role of Rare Earth Compound in the Catalytic System", J Polym Sci, Part A: Polym Chem, 2001, 39(16), 2751-2754.
2. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang "Copolymerization of Carbon Dioxide and Propylene oxide with Neodymium-Based Coordination Catalyst", Polymer. 2003, 44, 1803-1808.
3. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang " Thermal Degradation Kinetics of Poly (propylene carbonate) Obtained from Copolymerization of Carbon Dioxide and Propylene Oxide", J Appl Polym Sci, 2003, 90(4), 947-953.
4. Binyuan Liu, Zhixin Xue, Lu Liu, Li Zhang, Fang Liu “Modification and Characterization of Poly (ethylene-co-vinyl alcohol) by Glycosidations Reaction”,J Appl Polym Sci, 2006, 102 (1), 227-232.
5. Binyuan Liu, Chunying Tian, Li Zhang, Weidong, Yan, Wenjun Zhang “Copolymerization of Carbon Dioxide and Cyclohexene Oxide Using Zinc b-ketoiminato Complexes: Investigating the Influence of Electron Struacture of Zinc b-ketoiminato Complexes on the Catalytic Activity and Resultant Copolymer Properties”, J Polym Sci, Part A: Polym Chem, 2006,44,6243-6251.
6. Binyuan Liu, Yang Li, Li Zhang, Weidong Yan, Shuhuan Yao “Study on Thermal Degradation Kinetics of Poly (N-adamantyl-exo-nadIMIDE) Synthesized by Addition Polymerization”, J Appl Poly Sci , 2007, 103, 3003-3009.
7. Binyuan Liu, Yang Li, IL Kim,Boo-gyo Shin, Do Yeung Yoon, Li Zhang, Rongqin Ji, Weidong Yan “Thermal Characterization and Thermal Degradation of Poly (norbornene-2, 3-dicarboxylic acid dialkyl ester)s Synthesized by Vinyl Addition Polymerization”, Polym Degrad Stabl, 2007, 92, 868-875.
8. Binyuan Liu, Yang Li, Boo-Gyo Shin, Do Yeung Yoon, IL Kim, Li Zhang, Weidong Yan “Pd (II)-Catalyzed Vinyl Addition Polymerization of Novel Functionalized Norbornene Bearing Dimethyl Carboxylate Groups", J Polym Sci, Part A: Polym Chem, 2007, 45,3391-3399.
9. Binyuan Liu, Haiqing, Li, Weidong Yan, Chang-Sik IL Kim. “Ring-opening Polymerization of e-Caprolactone and Cyclohexene Oxide Initiated by Aluminum b-Ketoamino Complexes: Steric and Electronic Effect of 3-Position Substituents of the Ligands on Polymerization”, Macromol Res, 2008, 6(5), 441- 445.
10. Binyuan Liu, Yang Li, Anu Stell Mathews, Yige Wang, Weidong Yan, Sinoj Abraham, Chang-Sik Ha, Daewon Park, IL Kim. “Synthesis of Vinyl-type Functionalized Polynorbornene with Cyclic Pendant Imide Side Groups Using Palladium-Based Catalyst for Low Dielectric Constant Materials”, React Function Polym, 2008,68, 1619-1624.
11. Min Yang, Binyuan Liu, Luhai Wang, Hegang Ren, Wenyan Hu, Lifang Wen, Weidong Yan “Novel tandem catalytic system of β-diketonate zirconium/two different cocatalysts for preparing branched polyethylene”, Catal Commun, 2009, 10, 1427-1431.
12. Boo-Gyo Shin, Tai-Yon Cho, Do Y. Yoon,Binyuan Liu “Structure and Properties of Polynorbornene Derivatives. Poly(norbornene dicarboxylic acid dialkyl ester)s and Poly(norbornene dimethyl dicarboxylate)s”, Macromol Res, 2007, 15, 185.
13. Huanrong Li, Yige Wang, Wenjun Zhang, Binyuan Liu, Gion Calzaferri "Fabrication of oriented zeolite L monolayers employing luminescent perylenediimide-bridged silsesquioxane precursor as the covalent linker", Chem Commun, 2007, 2853-2854.
14. Yige Wang, Huanrong Li, Binyuan Liu, Quanying Gan, Qinglin Dong, Gion Calzaferri, Zheng Sun, “Fabrication of oriented zeolite L monolayer via covalent molecular linkers”, J Sold Stat Chem, 2008, 181, 2469-2472.
15. Peng Liu, Huanrong Li, Yige Wang, Binyuan Liu,Wenjun Zhang, Yanji Wang, Weidong Yan, Hongjie Zhang , Ulrich Schubert.Europium complexes immobilization on titania viachemical modification of titanium alkoxide”, J Mater Chem, 2008, 18, 735 – 737.
16. Yige Wang, Huanrong Li, Wenjun Zhang, Binyuan Liu, “Luminescene properties of nanozeolite L grafted with terbium organic complex”, Mater Lett, 2008, 62(17-18), 3167-3170.
17. Yige Wang, Li Wang, Huanrong Li, Peng Liu, Dashan Qin, Binyuan Liu, Wenjun Zhang, Ruiping Deng, Hongjie Zhang, “Synthesis and luminescene properties of hybrid organic-inorganic transparent titanin thin film actived by in-situ formed lanthanide complexes”,J Sold Stat Chem, 2008, 181, 562-566.
18. Huanrong Li, Huifang Shao, Yige Wang, Dashan Qin, Binyuan Liu, Wenjun Zhang, Weidong Yan. “Soft material with intense photoluminescence obtained by dissolving Eu2O3 and organic ligand into a task-specific ionic liquid”, Chem. Commun., 2008, 5209-5211.
19. 胡文艷, 楊敏, 趙辛, 劉賓元, 郝小宇, 閆衛東“β-二酮鋯/AlEt2C/MAO催化乙烯原位共聚合成支化聚乙烯(Synthesis of Branched Polyethylene from Ethylene via in situ Copolymerization Catalyzed by β-Diketonate Zirconium/AlEt2Cl/MAO)”, 高等學校化學學報, 2008, 29(2),430-432.
20. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Pange Liu “Functionalization of Three-Dimensionally Ordered Macroporous Cross-Linked Polystyrene by Atom-Transfer Radical Polymerization of Hydroxyethyl Methacrylate and Subsequent Derivatization” J Polym Sci, Part A: Polym Chem, 2008, 46, 7950-7959.
21. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Haiqing Li “Gaseous Infiltration Method for Preparation of Three-Dimensionally Ordered Macroporous Polyethylene”, Polymer, 2008, 49, 5446-5451.
22. 劉賓元,王曉亞,王弋戈,閆衛東,“降冰片烯醯亞胺的合成與表征”,化學試劑,2009,已錄用
23. 劉賓元,高延浩,趙鑫,閆衛東“新型水楊醛衍生物的合成”,化學試劑2009,已錄用
24. 毛彥科, 劉賓元,閆衛東“BP/THF引發體系引發降冰片烯與馬來酸酐可見光自由基共聚合”化工新型材料,2009,已錄用
25. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Pange Liu “Preparation and Characterization of Pore Wall-Functionalized Three-dimensionally Ordered Macroporous Syndiotactic Polystyrene”, Polym Eng Sci,2009, 49, 223-228.
26. Min Yang, Wei-dong Yan, Xiao-yu Hao, Binyuan Liu, Li-fang Wen, Pan-ge Liu “Tandem Catalytic Systems: One Catalyst Combined with Two Different Activators for Preparing Branched Polyethylene with Ethylene as Single Monomer” Macromolecular, 2009, 42, 905-907.
27. Weidong Yan, Xiaoyu Hao, Min Yang, Binyuan Liu, Pange Liu “Preparation of Branched Polyethylene by A Novel Tandem Catalytic System: rac-Et(Ind)2ZrCl2/AlEt2Cl/MAO”, J Polym Sci, Part A: Polym Chem 2009, 47, 1966-1970.
28. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Pange Liu “Graft Polymerization from Pore Wall of Three-dimensionally Ordered Macroporous Cross-linked Polystyrene via Atom Transfer Radical Polymerization”, Eur Polym J, 2009, 45, 1359-1366.
29. 張寧寧,劉賓元,王衛峰,任合剛,閆衛東,Z-N催化劑內給電子體作用機理的研究進展,合成樹脂與塑膠,2009, 26, 73-76.
教學論文 30. 閆衛東,劉賓元,張旭,張莉,現代條件下高校教師教學基本功的內容淺析,河北工業大學學報(成人教育學院學報),2008,23(4), 19-22.

本科生參與的論文

1. Modification and Characterization of Poly (ethylene-co-vinyl alcohol) by Glycosidations Reaction,
Binyuan Liu*, Zhixin Xue, Lu Liu, Li Zhang, Fang Liu
J Appl Polym Sci, 2006, 102 (1), 227-232. SCI077QO;EI20064110167651
2.丁醯化殼聚糖的製備及結構性能表征
劉賓元,王新利,張莉,閆衛東*,李曉然,
高分子科學與工程,2007,23,130-133. EI20072710691130
3. Study on Thermal Degradation Kinetics of Poly (N-adamantyl-exo-nadimide) Synthesized by Addition Polymerization,
Binyuan Liu*, Yang Li, Li Zhang, Weidong Yan, Shuhuan Yao
J Appl Poly Sci , 2007, 103, 3003-3009. SCI129YD; EI20071010472256
4. Addition Polymerizationof Functionalized Norbornene: Effects of pedant Imide Group on the Reactivity and Resulting Polymer Properties.
Binyuan Liu*, Xiaoya Wang, PeiWu, Weidong Yan,
International Symposium on Polymer Chemistry, PC2008, June15-19,2008,HeFei, China. P 129 (oral present)
5. Surface-confined radical chain transfer polymerization of methyl methacrylate on zirconium oxide nanoparticle
Binyuan Liu*, Ai Desheng, Li Yabin, Ji Rongqin, Liu Pange.
40 International Unin of Pure and Apllied Chemistry (IUPAC) Congress, Beijing, Preprint: 2005.
6. 新型二氧化碳與環氧化合物共聚催化劑
劉賓元,田春英, 章文軍, 王振,
2005年全國高分子學術論文報告會,北京
7. 糖苷化反應修飾聚(乙烯-乙烯醇)
劉賓元, 薛志欣,劉芳,劉璐
2005年全國高分子學術論文報告會,北京

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