![李金恆[湖南大學教授]](/img/8/d46/nBnauM3X3QTO1gTM4IDM2kzNxMTMwUTN5kTMxADMwAzMwIzLyAzL4EzLt92YucmbvRWdo5Cd0FmL0E2LvoDc0RHa.jpg "李金恆[湖南大學教授]")
簡介
李金恆出生於湖南永州。
李金恆學習工作履歷
2011–至今湖南大學，教授，博士生導師
2001–2010湖南師範大學，教授，博士生導師
2002–2004香港大學博士後
2000–2001中國科學院廣州化學研究所助研
2000–2002中國科學技術大學（在職）博士學位
1997–2000中國科學院廣州化學研究所碩士學位
1994–1997湖南農業大學助教
1990–1994湖南師範大學學士學位
主持基金項目情況
（1）國家自然科學基金青年項目“非臨界二氧化碳調控有機反應的研究”（No.20202002,2003.1–2005.12）。
（2）國家自然科學基金面上項目“胺作為配體在鈀催化交叉偶聯反應中套用研究”（No.20572020,2006.1–2008.12）。
（3）國家自然科學基金面上項目“芳基不飽和烴分子內親電自位環化反應合成螺環化合物的研究”（No.20872112,2009.1-20011.12）。
（4）教育部2006年度新世紀優秀人才支持計畫“過渡金屬催化偶聯反應中幾個基本問題的研究”（No.NCET-06-0711，2007.01-2009.12）
（5）霍英東教育基金會第十屆高等院校青年教師基金“叔胺作為配體在鈀催化偶聯反應中套用研究”（No.101012，2006.3-2008.3）
（6）教育部2006年度高等學校博士學科點專項科研基金項目“鈀和鹵化銅為催化體系的炔烴鹵鈀化反應及其在有機合成中套用研究”（No.20060542007，2007.01-2009.12）
（7）教育部科學技術研究重點項目“叔胺作為配體在鈀催化交叉偶聯反應中套用研究”（No.206102，2006.01~2007.12）。
（8）湖南省傑出青年基金項目“蛋白酶抑制劑3-亞甲基吲哚-2-酮衍生物合成新方法炔烴羰基化反應研究”（No.05JJ1002,2005.1–2007.12）。
（9）湖南省教育廳項目“過渡金屬催化炔芳構化反應研究”（No.02C211，2003.01-2004.12）。
（10）湖南省教育廳優秀青年項目“叔胺作為配體在鈀催化交叉偶聯反應中套用研究”（No.05B038，2005.01–2006.12）。
（11）湖南省教育廳重點項目“芳基不飽和烴分子內親電自位環化反應合成螺環化合物的研究”（8萬，08A037,2009-2011）。
（12）2008年浙江省科技計畫面上項目“抗腫瘤靶向藥物3-亞甲基吲哚酮合成技術開發與套用研究”（No.2008C33065，2008.01-2008.12）
（13）化學生物感測與計量學國家重點實驗室（湖南大學）項目“具有螢光特性的卟啉類化合物合成方法研究”（No.2006016,2007.3-2009.3）。
獲獎情況
（1）2010年廣東省科學技術獎一等獎（第四完成人）
（2）2009年度獲湖南省科學技術獎自然科學獎二等獎1項（第一完成人，項目名稱：過渡金屬鈀、銅催化構建C-C鍵和C-N鍵方法的研究）
（3）2006年度湖南省自然科學優秀學術論文一等獎;
（4）2004年度湖南省自然科學優秀學術論文一等獎;
（5）2001年度中國科技大學“張宗植“科技獎學金；
（6）2000年度中國科學院“院長優秀獎”獎學金；
（7）1999年度中國科學院“偉華”科技獎學金。
研究方向
主要研究興趣在有機合成方法學、金屬有機化學、藥物合成和綠色化學等幾方面：
（1）過渡金屬催化交叉偶聯反應；
（2）過渡金屬催化氧化環化串聯反應；
（3）套用發展出新的合成方法和技術，合成出具有抗腫瘤活性的靶向藥物。
部分代表性論文
1Zhi-QiangWang,YongLei,Ming-BoZhou,Guo-XiangChen,Ren-JieSong,Ye-XiangXie,andJin-hengLi,*Iron-Mediated[3+2]or[3+3]Annulationof2-(2-(Ethynyl)phenoxy)-1-arylethanones:SelectivesynthesisofIndeno[1,2-c]chromenesand5H-Naphtho[1,2-c]chromenes,Org.Lett.2011,13,14-17.
2YanLiu,BoYao,Chen-LiangDeng,*Ri-YuanTang,Xing-GuoZhang,andJin-HengLi,*Palladium-catalyzedSelectiveheck-TypeDiarylationofAllylicEsterswithArylHalidesInvolvingaβ-OACEliminationProcess,Org.Lett.,2011,13,1126–1129.
3Liu,Y.;Yao,B.;Deng,C.-L.;*Tang,R.-Y.;Zhang,X.-G.;Li,J.-H.*Palladium-CatalyzedOxidativeCouplingofTrialkylamineswithArylIodidesLeadingtoAlkylArylKetones,Org.Lett.,2011,13,2184-2187.
4YongLei,Zhi-QiangWang,Ye-XiangXie,Shang-CiYu,Bo-XiaoTang,andJin-HengLi,*Base-MediatedTandemReactionConsistingofAnAcylShiftStrategyLeadingto4,5-DisubstiutedFuran-2(5H)-ones,Adv.Synth.Catal.2011,353,31-35.
5Huang-CheOuyang,Ri-YuanTang,PingZhong,*Xing-GuoZhang,andJin-HengLi*CuI/I2-PromotedElectrophilicTandemCyclizationof2-Ethynylbenzaldehydeswithortho-Benzenediamines:SynthesisofIodoisoquinoline-fusedBenzimidazoles,J.Org.Chem.2011,76,223-226.
6Ren-JieSong,YuLiu,Yan-YunLiu,andJin-HengLi,*Palladium-CatalyzedconjugateAdditiontoElectron-deficientAlkyneswithBenzenesulfinicAcidDerivedfrom1,2-Bis(phenylsulfonyl)ethane:SelectiveSynthesisof(E)-VinylSulfones,J.Org.Chem.2011,76,1001–1004.
7Hong-PingZhang,Shang-CiYu,Yun,Liang,PengPeng,Bo-XiaoTang,andJin-HengLi*HalopalladationCyclizationofAlkyneswithAzides:SelectiveSynthesisof4-Haloisoquinolinesand3-Haloindoles,Synlett2011,982-988.
8Xiao-LiFang,Ri-YuanTang,Xing-GuoZhang,*andJin-HengLi*,FeF3/I2-CatalyzedSynthesisof4-Chalcogen-SubstitutedArylaminesbyDirectThiolationofanAreneC-HBond,Synthesis2011,1099-1105.
9Hong-PingZhang,Xu-HengYang,PengPeng,andJin-HengLi,*PdI2/I2-CatalyzedThiolationAnnulationsof2-AlkynylBenzylAzideswithDisulfides:SelectiveSynthesisof4-Sulfenylisoquinolines,Synthesis2011,1219-1226.
10Xiao-LiFang,Ri-YuanTang,Xing-GuoZhang,PingZhong,*Chen-LiangDeng,Jin-HengLi*ZnCl2-catalyzed[4+2]benzannulationof2-ethynylbenzaldehydeswithalkynes:selectivesynthesisofnaphthalenederivatives,J.Organometal.Chem.2011,696,352-356.
11Bo-XiaoTang,Ren-JieSong,Cui-YanWu,YuLiu,Ming-BoZhou,Wen-TingWei,Guo-BoDeng,Du-LinYin,andJin-HengLi,*Copper-CatalyzedIntramolecularC-HOxidation/AcylationofFormyl-N-arylformamidesLeadingtoIndoline-2,3-diones,J.Am.Chem.Soc.2010,132,8900–8902.
12Ri-YuanTang,Jin-HengLi,*PdCl2-CataylzedDominoReactionsof2-AlkynylbenzaldehydeswithIndoles:SynthesisofFluorescent5H-Benzo[b]carbazol-6-ylKetones,Chem.Eur.J.2010,16,4733-4738.
13Rong-JiangLi,Shao-FengPi,YunLiang,*,Zhi-QiangWang,Ren-JieSong,Guo-XiangCheng,andJin-HengLi*Palladium-CatalyzedAnnulationsofAryneswith2-(2-Iodophenoxy)-1-substitutedethanonesthrougha-ArylationofKetones,Chem.Commun.2010,46,8183–8185.
14Shao-FengPi,Xu-HengYang,Xiao-ChengHuang,YunLiang,*Guan-NanYang,Xiao-HongZhang,andJin-HengLi,*Palladium-CatalyzedCyclocarbonylationofAryneswithMethylAllylCarbonates:SelectiveSynthesisof1H-Inden-1-onesJ.Org.Chem.2010,75,3484–3487.
15Wen-WuZhang,Xing-GuoZhang,andJin-HengLi,*Palladium-CatalyzedDecarboxylativeCouplingofAlkynylCarboxylicAcidswithBenzylHalidesorArylHalides,J.Org.Chem.2010,75,5259-5264.
16Ming-BoZhou,Wen-TingWei,Ye-XiangXie,YongLei,andJin-HengLi,*Palladium-CatalyzedCross-CouplingofElectron-PoorTerminalAlkyneswithArylboronicAcidsunderLigand-FreeandaerobicConditions,J.Org.Chem.2010,75,5635–5642.
17Shu-XiangDong,Xing-GuoZhang,*QiongLiu,Ri-YuanTang,PingZhong,Jin-HengLi,*Synthesisof1-Substituted-2-(trifluoromethyl)indolesviaPalladium-CatalyzedDoubleAminationReaction,Synthesis2010,1521-1525.
18Jian-ShengTang,Ye-XiangXie,Zhi-QiangWang,Chen-LiangDeng,andJin-HengLi,*PhosphazeneBase-CatalyzedIntramolecularCascadeReactionsofAryl-SubstitutedEnynes,Synthesis2010,3204-3210.
19YuLiu,Ren-JieSong,andJin-HengLi,*Yb(OTF)3-PromotedZnCl2-CatalyzedConia-eneReactionsofLinearβ-Alkynicβ-Dicarbonyls,Synthesis2010,3663-3669.
20Ri-YuanTang,Pei-SongLuo,Xing-GuoZhang,PingZhong,andJin-HengLi,*Silver-CatalyzedAmmonolysis-CyclizationTandemReactionsof2-AlkynylbenzenamineswithTetraalkylthiuramDisulfidesLeadingto4-Methylene-4H-benzo[d][1,3]thiazin-2-amines,Synlett2010,1345-1350.
21XiaZhao,Xing-GuoZhangRi-YuanTang,Chen-LiangDeng,Jin-HengLi,*ZnI2-CatalyzedBenzannulationofo-AlkynylbenzaldehydeswithAlkenesLeadingto1-Acyl-2-substitutednaphthalenes,Eur.J.Org.Chem.2010,4211-4217.
22Yan-JinGuo,Ri-YuanTang,PingZhong,Jin-HengLi*Copper-CatalyzedTandemReactionsof2-HalobenzenamineswithIsothiocyanatesunderLigandandBase-FreeConditions,TetrahedronLett.2010,51,649-652.
23WANGFeng,TANGBoxiao,XIEYexiang,*LIJinheng,*SynthesisofAlkyl-ArylEthersbyCopper-catalyzedEtherizationReactionofArylFluorideswithTetraalkylammoniumBromidesandH2OinthePresenceofBase,Chin.J.Chem.2010,28,2318-2312.
24Zhi-QiangWang,YunLiang,YongLei,Ming-BoZhouaandJin-HengLi*Iron-catalyzedannulationsof2-(2-alkynyl)phenoxy)-1-arylethanonesleadingtosubstitutednaphthalen-1-ols,Chem.Commun.2009,5242–5244.
25Tao-ShanJiangandJin-HengLiPalladium-catalyzedoxidativetandemreactionofallylamineswitharylhalidesleadingtounsaturatedaldehydes,Chem.Commun.2009,7236-7238.
26Chen-LiangDeng,Ren-JieSong,Yi-Lin-Liu,Jin-HengLi,*GerneralZinc-CatalyzedConia-EneReactionsof1,3-dicarbonlyCompoundswithAlkynesIncludingtheClasssicallyChallengingSubstratesunderNeatConditions,Adv.Synth.Catal.2009,351,3096–3100.
27Yan-JinGuo,Ri-YuanTang,Jin-HengLi,*PingZhong,andXing-GuoZhang*Palladium-CatalyzedAnnulationof2-(1-Alkynyl)benzenamineswithDisulfides:Synthesisof3-Sulfenylindoles,Adv.Catal.Synth.2009,351,2615-2618.
28Jing-WenQiu,Xing-GuoZhang,Ri-YuanTang,PingZhong,andJin-HengLi*Iron-CatalyzedTandemReactionsof2-HalobenzenamineswithIsothiocyanatesLeadingto2-Aminobenzothiazoles,Adv.Catal.Synth.2009,351,2319-2323.
29Zou,T.;Pi,S.-S.;Li,J.-H.*FeCl3-Catalyzed1,2-AdditionReactionsofArylAldehydeswithArylboronicAcids,Org.Lett.2009,11,453-456.
30Huang,X.-C.;Wang,F.;Liang,Y.;*Li,J.-H.*Halopalladation/Decarboxylation/Carbon−CarbonFormingDominoProcess:Synthesisof5-Halo-6-substitutedBenzo[b]naphtho[2,1-d]furans,Org.Lett.2009,11,1139-1142.
31Shao-FengPi,Bo-XiaoTang,Jin-HengLi*,Yi-LinLiuandYunLiang,*Palladium-CatalyzedDecarboxylativeCouplingofAllylicAlkynoateswithArynes,Org.Lett.,2009,11,2309-2312.
32Deng,C.-L.;Zou,T.;Wang,Z.-Q.;SongR.-J.;Li,J.-H.*Copper/Silver-CocatalyzedConia-EneReactionsof2-Alkynic1,3-DicabonylCompounds,J.Org.Chem.2009,74,412-414.
33Liu,Y.-L.;Liang,Y.;Pi,S.-F.;Huang,X.-C.;Li,J.-H.*Palladium-CatalyzedCocyclotrimerizationofAlleneswithArynes:SelectiveSynthesisofPhenanthrenes,J.Org.Chem.2009,74,3199–3202.
34Peng,P.;Tang,B.-X.;Pi,S.-F.;Liang,Y.;Li,J.-H.*Synthesisof(E)-3-(Isobenzofuran-3(1H)-ylidene)indolin-2-onesbyPalladium-CatalyzedIntramolecularC-HFunctionalizationProcess,J.Org.Chem.2009,74,3569-3572.
35Yi-LinLiu,YunLiang,*Shao-FengPi,Jin-HengLi*SelectiveSynthesisofo-AcetylbenzylphosphonatesbyInsertionReactionsofArynesintoβ-Ketophosphonates,J.Org.Chem.2009,74,5691-5694.
36Dong-JunTang,Bo-XiaoTang,andJin-HengLi*SelectiveSynthesisof3-ArylQuinolin-2(1H)-onesand3-(1-Arylmethylene)oxindolesInvolvinga2-FoldAreneC-HActivationProcess,J.Org.Chem.2009,74,6749–6755.
37Hui-AiDu,Xing-GuoZhang*,Ri-YuanTang,andJin-HengLi*PdCl2-PromotedElectrophilicAnnulationof2-AlkynylphenolDerivativeswithDisulfidesorDiselenidesinthePresenceofiodine,J.Org.Chem.2009,74,7844–7848.
38Tao-ShanJiang,Ri-YuanTang,Xing-GuoZhang,Xin-HuaLi,Jin-HengLi*Palladium-CatalyzedIntramolecular5-exo-digHydroarylationsofN-Arylpropiolamides:thermodynamics-ControlledStereoselectiveSynthesisof3-Methyleneoxindoles,J.Org.Chem.2009,74,8834-8837.
39Wang,Z.-Q.;Tang,B.-X.;Zhang,H.-P.;Wang,F.;Li,J.-H.*Electrophilicipso-HalocyclizationofN-ArylpropiolamideswithPolyfluoroalkylAlcohols:SelectiveSynthesisof8-(Polyfluoroalkoxy)azaspiro[4,5]trienes,Synthesis2009,891-902.
40Luo,P.-S.;Wang,F.;LiJ.-H.;*Tang,R.-Y.;Zhong,P.*Copper-CatalyzedSelectiveS-Arylationof1,2-Bis(o-amino-1H-pyrazolyl)disulfideswithArylboronicAcids,Synthesis2009,921-928.
41Tao-ShanJiang,Xing-GuoZhang,andJin-HengLi*IodocyclizationofN-(2-Methylthiophenyl)propiolamides:SelectiveSynthesisof3-Iodo-1,5-benzothiazepin-4-ones,Synthesis2009,3029-3038.
42Xiao-liFang,Ri-YuanTang,PingZhong,Jin-HengLi*Iron-CatalyzedSulfenylationofIndoleswithDisulfidesPromotedbyaCatalyticAmountofIodine,Synthesis2009,4183-4189.
43Sha-ShaPi,Xing-GuoZhang,Ri-YuanTang,Jin-HengLi*Copper-CatalyzedTandemReactionof2-HaloanilineDerivativeswithTetraalkylthiuramDisulfides:SelectiveSynthesisof2-Aminobenzothiazoles,Synlett2009,3032-3036.
44Luo,P.-S.;Yu,M.Tang,R.-Y.;*Zhong,P.;LiJ.-H.*Solvent-freecopper-catalyzedoxidativeS-arylationof1,2-diaryldisulfideswitharyltrimethoxysilane,TetrahedronLett.2009,50,1066-1070.
45Ren-JieSong,YuLiu,Rong-JiangLi,andLi,J.-H.*Selectivesynthesisof3-methyleneindolin-2-onesbyone-potmulticatalyticprocesses,TetrahedronLett.2009,50,3912-3916.
46Yu,M.;Tang,R.-Y.;LiJ.-H.*Synthesisof6,7-dihydro-5H-dibenzo[c,e]azepinesandbiarylsbypalladiumcatalyzedUllmannreaction,Tetrahedron2009,65,3409-3416.
47ZhijuanCao,YulongHu,WeiWu,TuanzhuHa,JimKelley,ChenliangDeng,QiChen,ChuanfuLi,JinhengLi*,andYuehuaLi*TheTIR/BB-loopmimeticAS-1protectsthemyocardiumfromischaemia/reperfusioninjury,CardiovascularResearch2009,84,442–451.
48TAOLiming,XIEYexiang,*DENGChenliang,LIJin-heng*GenerationofPdNanoparticlesinsitufromPdCl2inTBAF:anEfficientandReusableCatalyticSystemfortheSuzuki-MiyauraReactionunderLigand-andSolvent-freeConditions,Chin.J.Chem.2009,27,1365-1373..
49羅培松湯日元鍾平,李金恆,炔烴分子內環化反應合成含氮雜環化合物研究進展,有機化學,2009,29,1924-1937.
50Tang,B.-X.;Tang,D.-J.;Tang,S.;Yu,Q.-F.;Zhang,Y.-H.;Liang,Y.;Zhong,P.;Li,J.-H.*SelectiveSynthesisofSpiro[4,5]trienylAcetatesviaAnIntramolecularElectrophilicipso-IodocyclizationProcess,Org.Lett.2008,10,1063-1066.
51Tang,S.;Peng,P.;Pi,S.-F.;Liang,Y.;Wang,N.-X.;*Li,J.-H.*SequentialIntermolecularAminopalladation/ortho-AreneC-HActivationReactionsofN-PhenylpropiolamideswithPhthalimide,Org.Lett.2008,10,1179-1182.
52Huang,X.-C.;Liu,Y.-L.;Liang,Y.;*Pi,S.-F.;Wang,F.;Li,J.-H.*CycloadditionofAryneswithIodoniumYlides:AMildandGeneralRoutefortheSynthesisofBenzofuranDerivatives,Org.Lett.2008,10,1525-1528.
53Tang,S.;Peng,P.;Wang,Z.-Q.;Tang,B.-X.;Deng,C.-L.;Li,J.-H.*;Zhong,P.;Wang,N.-X.Synthesisof(2-Oxoindolin-3-ylidene)methylAcetatesInvolvingaC−HFunctionalizationProcess,Org.Lett.2008,10,1875-1878.
54Yu,Q.-F.;Zhang,Y.-H.;Yin,Q.;Tang,B.-X.;Tang,R.-Y.;PingZhong,P.;Li,J.-H.*Electrophilicipso-IodocyclizationofN-(4-Methylphenyl)propiolamides:SelectiveSynthesisof8-Methyleneazaspiro[4,5]trienes,J.Org.Chem.2008,73,3658-3661.
55Tang,S.;Peng,P.;Zhong,P.;Li,J.-H.*Palladium-CatalyzedC-HFunctionalizationofN-ArylpropiolamideswithAryliodoniumSalts:SelectiveSynthesisof3-(1-Arylmethylene)oxindoles,J.Org.Chem.2008,73,5476-5480.
56Tang,B.-X.;Yin,Q.;Tang,R.-Y.;Li,J.-H.*Electrophilicipso-CyclizationofN-(p-Methoxyaryl)propiolamidesInvolvingAnElectrophile-ExchangeProcess,J.Org.Chem.2008,73,9008–9011.
57Tang,B.-X.;Guo,S.-M.;Zhang,M.-B.;Li,J.-H.*N-ArylationsofNitrogen-ContainingHeterocycleswithArylandHeteroarylHalidesUsingCu2ONanoparticles/1,10-PhenanthrolineCatalyticSystem,Synthesis2008,1707-1716.
58Liang,Y.;Tao,L.-M.;Zhang,Y.-H.;Li,J.-H.*Palladium-CatalyzedCross-CouplingReactionsof1,2-DiiodoalkeneswithTerminalAlkynes:SelectivelySynthesisofUnsymmetric1,3-Butadiynesand2-Ethynylbenzofurans,Synthesis2008,3988.
59Wang,Z.-L.;Tang,R.-Y.;*Luo,P.-S.;Deng,C.-L.;Zhong,P.;Li,J.-H.*HydrothiolationofTerminalAlkyneswithDiarylDisulfidesandDiphenylDiselenide:SelectiveSynthesisof(Z)-1-AlkenylSulfidesandSelenides,Tetrahedron2008,64,10670-10675.
60Xie,Y.-X.;Wang,J.;Li,J.-H.;*Liang,Y.*ReusableandLigand-FreePalladium-CatalyzedSuzuki-MiyauraCross-CouplingsofArylHalideswithArylboronicAcidsinTBAB,Chin.J.Chem.2008,26,2261-2266.
61Deng,C.-L.;Song,R.-J.;Guo,S.-M.;Wang,Z.-Q.;Li,J.-H.*Copper/Silver-CocatalyzedConia-EneReactionofLinearb-Alkynicb-Ketoesters,Org.Lett.2007,9,5111-5114.
62Tang,S.;Yu,Q.-F.;Peng,P.;Li,J.-H.*;Zhong,P.;TangR.-Y.Palladium-CatalyzedCarbonylativeAnnulationReactionof2-(1-Alkynyl)benzenamines:SelectiveSynthesisof3-(Halomethylene)indolin-2-ones,Org.Lett.2007,9,3413-3416.
63Li,J.-H.*;Li,J.-L.;Wang,D.-P.;Pi,S.-F.;Xie,Y.-X.;ZhangM.-B.;Hu,X.-C.CuI-CatalyzedSuzuki-MiyauraandSonogashiraCross-CouplingReactionsUsingDABCOasLigand,J.Org.Chem.2007,72,2053-2057.
64Tang,B.-X.;Wang,F.;Li,J.-H.*;Xie,Y.-X.;ZhangM.-B.ReusableCu2O/PPh3/TBABSystemfortheCross-CouplingsofArylHalidesandHeteroarylHalideswithTerminalAlkynes,J.Org.Chem.2007,72,6294-6297.
65Liang,Y.;Xie,Y.-X.;Li,J.-H.*Cy2NH×HX-PromotedCyclizationsofo-(1-Alkynyl)benzoatesand(Z)-2-Alken-4-ynoatewithCopperHalidestosynthesizeIsocoumarinsanda-Pyrone,Synthesis2007,400-406.
66Li,J.-H.*;Li,J.-L.;Xie,Y.-X.TBAB-PromotedLigand-FreeCopper-CatalyzedCross-CouplingReactionsofArylHalideswithArylboronicAcids,Synthesis2007,984-988.
67Tang,S.;Li,J.-H.*;Xie,Y.-X.;WangN.-X.*HalogenationsofIndoleswithCuX2:SelectiveSynthesisof2-Halo-,3-Halo-and2,3-Dibromoindoles,Synthesis2007,1535-1541.
68Tang,S.;Xie,Y.-X.;Li,J.-H.*;WangN.-X.*PdX2/CuX2-CatalyzedAnnulationof2-Ethynylbenzenamines:SelectiveSynthesisof3-Halo-2-substituted-1H-indoles,Synthesis2007,1841-1847.
69Li,J.-H.*;Zhang,Y.-H.;Song,R.-J.;Xie,Y.-X.;Deng,C.-L.;Liang,Y.b-KetoAmides:inexpensiveandEfficientLigandsforthePalladium-CatalyzedSuzuki-MiyauraCross-CouplingReaction,Synthesis2007,2957-2966.
70Deng,C.-L.;Guo,S.-M.;Xie,Y.-X.;Li,J.-H.*Mildandligand-freepalladium-catalyzedcross-couplingsofarylhalideswitharylboronicacidstosynthesizebiarylsandheterocycle-containingbiaryls,Eur.J.Org.Chem.2007,1457-1462.
71Song,R.-J.;Deng,C.-L.;Xie,Y.-X.;Li,J.-H.*Solvent-freecopper/ironco-catalyzedN-arylationreactionsofnitrogen-containingheterocycleswithtrimethoxysilanesinair,TetrahedronLett.2007,44,7845-7848.
72Guo,S.-M.;Deng,C.-L.;Li,J.-H.*Cu(OAc)2-CatalyzedSonogashiraCross-couplingReactioninAmines,Chin.Chem.Lett.2007,18,13-16.
73Li,J.-H.*;Deng,C.-L.;Xie,Y.-X.Solvent-FreePalladium-CatalyzedSuzuki-MiyauraCross-CouplingsofArylChlorideswithArylboronicAcids,Synth.Commun.2007,37,2433-2448.
74唐石，王乃興*，李金恆*，不飽和烴Heteropalladation反應在有機合成中的套用，有機化學，2007，27，819-829.
75陶李明，梁雲，李金恆*，末端炔烴二聚反應合成共軛烯炔的研究進展，有機化學，2007，27，1078-1086.
76Liang,Y.;Tang,S.;Zhang,X.-D.;Mao,L.-Q.;Xie,Y.-X.;Li,J.-H.*NovelandSelectivePalladium-CatalyzedAnnulationsof2-AlkynylphenolsToForm2-Substituted3-Halobenzo[b]furans,Org.Lett.2006,8,3017-3020.
77Liang,Y.;Xie,Y.-X.;Li,J.-H.*GeneralandModifiedPalladium-CatalyzedSonogashiraCross-CouplingReactionunderCopper-,Amine-andSolvent-FreeConditions,J.Org.Chem.2006,71,379-381.
78Li,J.-H.*;Tang,B.-X.;Tao,L.-M.;Liang,Y.;Zhang,M.-B.*ReusableCopper-CatalyzedCross-CouplingReactionsofArylHalideswithOrganotinsinInexpensiveIonicLiquids,J.Org.Chem.2006,71,7488-7490.
79Xie,Y.-X.;Pi,S.-F.;Wang,J.;Yin,D.-L.;Li,J.-H.*2-Aminopyrimidine-4,6-diolasanEfficientLigandforSolvent-FreeCopper-CatalyzedN-ArylationsofImidazoleswithArylandHeteroarylHalides,J.Org.Chem.2006,71,8324-8327.
80Liu,W.-J.;Xie,Y.-X.;Liang,Y.;Li,J.-H.*ReusableandEfficientPd(OAc)2/TBAB/PEG-400SystemforSuzuki-MiyauraCross-CouplingReactionUnderLigand-FreeConditions,Synthesis2006,860-864.
81Li,J.-H.;*Deng,C.-L.;Xie,Y.-X.ImprovedProcedureforPalladium-CatalyzedHiyamaCross-CouplingReactionofArylHalideswithAryltrimethoxysilanesunderSolvent-FreeConditions,Synthesis2006,969-974.
82Deng,C.-L.;Xie,Y.-X.;Yin,D.-L.Li,J.-H.*Cu(OAc)2/DAB-Ph-CatalyzedSonogashiraCross-CouplingsofArylHalideswithTerminalAlkynesunderAerobicandSolvent-FreeConditions,Synthesis2006,3370-3376.
83Li,J.-H.;*Hu,X.-C.;Liang,Y.;Xie,Y.-X.PEG-400PromotedPd(OAc)2/DABCO-CatalyzedCross-CouplingReactioninAqueousMedia,Tetrahedron2006,62,31-38.
84Li,J.-H.;*Zhu,Q.-M.;Xie,Y.-X.Pd(OAc)2/DABCO-catalyzedSuzuki-Miyauracross-couplingreactioninDMF,Tetrahedron2006,62,10888-10895.
85Li,J.-H.;*Hu,Q.-C.;Xie,Y.-X.Polymer-SupportedDABCO-PalladiumComplexasAStableandReusableCatalystforRoomTemperatureSuzuki-MiyauraCross-CouplingsofArylBromides,TetrahedronLett.2006,47,9239-9243.
86Li,J.-H.;*Wang,D.-P.CuI/DABCO-catalyzedcross-couplingreactionsofarylhalideswitharylboronicacids,Eur.J.Org.Chem.2006,2063-2066.
87Gao,Q.;Zheng,B.-F.;Li,J.-H.;Yang,D.*Ni(II)-CatalyzedConia-EneReactionof1,3-DicarbonylCompoundswithAlkynes,Org.Lett.2005,7,2185-2188.
88Yip,K.-T.;Li,J.-H.;Lee,O.-Y.;Yang,D.*AerobicOxidativeCyclizationunderPd(II)Catalysis:ARegioselectiveApproachtoHeterocycles,Org.Lett.20057,5717-5719.
89Li,J.-H.;*Tang,S.;Xie,Y.-X.GeneralandSelectiveSynthesisof(Z)-3-HaloacrylatesviaPalladium-CatalyzedCarbonylationofTerminalAlkynes,J.Org.Chem.2005,70,477-479.
90Li,J.-H.;*Liang,Y.;Wang,D.-P.;Liu,W.-J.;Xie,Y.-X.;Yin,D.-L.EfficientStilleCross-CouplingReactionCatalyzedbyPd(OAc)2/DabcoCatalyticSystem,J.Org.Chem.2005,70,2832-2834.
91Li,J.-H.;*Liang,Y.;Xie,Y.-X.EfficientPalladium-CatalyzedHomocouplingReactionandSonogashiraCross-CouplingReactionofTerminalAlkynesunderAerobicConditions.J.Org.Chem.2005,70,4393-4396.
92Li,J.-H.;*Zhu,Q.-M.;Liang,Y.;YangD.EfficientandReusablePdCl2(MECN)2/CuCl2/PEG-400SystemforCyclizationofAlkenylKetoEstersandAmides,J.Org.Chem.2005,70,5347-5349.
93Li,J.-H.;*Liu,W.-J.;Xie,Y.-X.RecyclableandReusablePd(OAc)2/DABCO/PEG-400SystemforSuzuki-MiyauraCross-CouplingReaction,J.Org.Chem.2005,70,5409-5412.
94Li,J.-H.;*Wang,D.-P.;Xie,Y.-X.CuI/DabcoasaHighlyActiveCatalyticSystemfortheHeck-TypeReaction,TetrahedronLett.2005,46,4941-4944.
95Li,J.-H.;*Liang,Y.;Zhang,X.-D.Amine-andphosphine-freepalladium(II)-catalyzedhomocouplingreactionofterminalalkynes,Tetrahedron2005,61,1903-1907.
96Li,J.-H.;*Liang,Y.;Xie,Y.-X.EfficientStilleCross-CouplingReactionCatalyzedbyPd(OAc)2/DAB-CyCatalyticSystem,Tetrahedron2005,61,7289-7293.
97Li,J.-H.;*Zhang,X.-D.;Xie,Y.-X.EfficientandCopper-FreePd(OAc)2/Dabco-catalyzedSonogashiraCross-CouplingReaction,Synthesis2005,804-808.
98Li,J.-H.;*Wang,D.-P.;Xie,Y.-X.Pd(OAc)2/DabcoasaHighlyActiveCatalyticSystemfortheHeckReaction,Synthesis2005,2193-2197.
99Li,J.-H.;*Deng,C.-L.;Liu,W.-J.;Xie,Y.-X.Pd(OAc)2/DABCOasanInexpensiveandEfficientCatalyticSystemforHiyamaCross-CouplingReactionsofArylHalideswithAryltrimethoxysilanes,Synthesis2005,3039-3044.
100Li,J.-H.;*Zhang,X.-D.;Xie,Y.-X.EfficientPd(OAc)2/PyrimidinesCatalyticSystemforSuzuki-MiyauraCross-CouplingReaction,Synlett2005,1897-1900.
101Li,J.-H.;*Zhang,X.-D.;Xie,Y.-X.Efficientandcopper-freeSonogashiracross-couplingreactioncatalyzedbyPd(OAc)2/pyrimidinescatalyticsystem,Eur.J.Org.Chem.2005,4256-4259.
102Li,J.-H.;*Liu,W.-J.DabcoasanInexpensiveandHighlyEfficientLigandforPalladium-CatalyzedSuzuki-MiyauraCross-CouplingReaction,Org.Lett.2004,6,2809-2811.
103Li,J.-H.;*Liang,Y.;Xie,Y.-X.MildandSelectivePalladium-CatalyzedDimerizationofTerminalAlkynesToForm(Z,Z)-1,4-Dihalo-1,3-dienes,J.Org.Chem.2004,69,8125-8127.
104Li,J.-H.;*Xie,Y.-X.;Yin,D.-L.NewRoleofCO2asASelectiveAgentinPalladium-CatalyzedReductiveUllmannCouplingwithZincinWater,J.Org.Chem.2003,68,9867-9869.
105Li,J.-H.;*Xie,Y.-X.;Jiang,H.-F.;Chen,M.-C.Palladium-CatalyzeUllmann-TypeCouplingwithZincinthePresenceofH2OinLiquidCarbonDioxide,GreenChem.2002,4,424.
106Li,J.-H.;*Xie,Y.-X.;Yin,D.-L.NewroleofcarbondioxideinLewisassistedBrostedacidaccelerateddiiodinationofalkynesinwater,GreenChem.2002,4,505.
107Yang,D.;*Li,J.-H.;Gao,Q.;Yan,Y.-L.lanthanideTriflatesPromotedPalladium-CatalyzedCyclizationofAlkenylb–KetoEstersandAmides,Org.Lett.2003,5,2869-2871.
108Li,J.-H.;Jiang,H.-F.;*Chen,M.-C.CuCl2-inducedregiospecificalsynthesisofbenzenederivativesinthepalladium-catalyzedcyclotrimerizationofalkynes,J.Org.Chem.2001,66,3627-3629.
109Li,J.-H.;Jiang,H.-F.;*Chen,M.-C.*respectiveconversionofn-butylaminetomethylN-n-butylcarbamateandoxalbutylineinsupercriticalcarbondioxide,GreenChem.2001,3,137.
110Li,G.-P.;Jiang,H.-F.;*Li,J.-H.UseWaterasaDirectHydrogendonorinSupercriticalCarbonDioxide:ANovelandEfficientZn-H2O-CO2SystemforSelectiveReductionofAldehydestoAlcohols,GreenChem.2001,3,250.
111Li,J.-H.;Li,G.-P.;Jiang,H.-F.;*Chen,M.-C.*Anovelandefficientsynthesisofmaleicanhydridesbypalladium-catalyzeddicarbonylationofterminalacetylenesinH2O/Dioxane,TetrahedronLett.2001,42,6923-6924.
112Li,J.-H.;Jiang,H.-F.;*Feng,A.-Q.;Jia,L.-Q.Novelstereospecificsynthesesof3-chloroacrylateestersviapalladium-catalyzedcarbonylationofterminalacetylenes.J.Org.Chem.1999,64,5984-5987.
113Jia,L.-Q.;Jiang,H.-F.;*Li,J.-H.Palladium(Ⅱ)-catalyzedoxidationofacrylateesterstoacetalsinsupercriticalcarbondioxide.Chem.Commun.1999,985.
114Li,J.-H.;Jiang,H.-F.;*Jia,L.-Q.Glassercouplingreactioninsupercriticalcarbondioxide,Chem.Commun.1999,2369.
115Jia,L.-Q.;Jiang,H.-F.;*Li,J.-H.SelectivecarbonylationofnorborneneinscCO2:palladium(II)-catalyzedcarbonylationofnorborneneinsupercriticalcarbondioxide.GreenChem.1999,1,91.
湖南大學教授
| 湖南大學是歷史悠久、聲譽斐然的著名大學，現為教育部直屬全國重點大學，國家“211工程”、“985工程”重點建設高校。 |
